Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.201-206
Magnetic Properties of Ni/BN/Co Trilayer Structure: A First Principles Study
Using the Vienna ab initio simulation package (VASP) incorporating both semiempirical and nonlocal van der Waals interaction, the structural, adsorption, and magnetic properties of Ni/BN/Co systems were investigated. We proposed that the relative spin direction of Ni and Co magnets can be easily tuned, because the total energy difference between ferromagnetic (FM) and antiferromagnetic (AFM) states is small. Despite this feature, very interestingly, both Ni and Co layers manifest half-metallic state, whereas the spacer BN layer becomes weak metal for one monolayer (ML) thickness and an insulating barrier for two ML thicknesses. The half-metallic behavior of the magnetic layers seems very robust, because it is independent of the magnetic coupling between Ni and Co. This finding indicates that the Ni/BN/Co system can be used as a potential candidate for tunneling magnetoresistance system.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.207-210
Dependence of Structural and Magnetic Properties on Annealing Times in Co-precipitated Cobalt Ferrite Nanoparticles
Modifications in the structural and magnetic properties of co-precipitated cobalt ferrite nanoparticles can be accomplished by varying the annealing time periods during the synthetic process. Experimental results show that high-purity cobalt ferrite nanoparticles are obtained using a co-precipitation process. The dependence of the crystallite sizes on the annealing time was successfully demonstrated using XRD and SEM. Finally, vibrating sample magnetometer analyses show that the magnetic properties of the cobalt ferrite nanoparticles depend on their relative particle sizes.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.211-214
Structure and Magnetic Properties of Cr2O3/CrO2 Nanoparticles Prepared by Reactive Laser Ablation and Oxidation under High Pressure of Oxygen
Cr2O3 nanoparticles were prepared via one-step reactive laser ablation of Cr in oxygen. The metastable CrO2 phase was obtained through the subsequent oxidation of Cr2O3 nanoparticles under O2 with gas pressures of up to 40 MPa. The as-prepared Cr2O3 nanoparticles are spherical or rectangular in shape with sizes ranging from 20 nm to 50 nm. High oxygen pressure annealing is effective in producing meta-stable CrO2 from as-dried Cr2O3 nanoparticles, and the Cr2O3 nanoparticles exhibit a weak ferromagnetic behavior with an exchange bias of up to 11 mT that can be ascribed to the interfacial exchange coupling between uncompensated surface spins and the antiferromagnetic core. The Cr2O3/CrO2 nanoparticles exhibit an enhanced saturation magnetization and a reduced exchange bias with an increasing faction of CrO2 due to the elimination of uncompensated surface spins over the Cr2O3 nanoparticles when exposed to a high pressure of O2 and/or possible phase segregation that results in a smaller grain size for both Cr2O3 and CrO2.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.215-220
Thermo-sensitive Electrospun Fibrous Magnetic Composite Sheets
The PVDF fibrous composite filled with iron oxide nanoparticles were prepared by using the electrospinning technique. The electrospun composite have the thickness in the range of 60-80 μm with the average fibrous diameters of 500-900 nm. The magnetizations of PVDF fibrous composite filled with iron oxide nanoparticles showed 4.5 emu/g, 3.1 emu/g and 1.6 emu/g at 1.5 T of external magnetic field for 20 wt.%, 10 wt.% and 5 wt.% iron oxide nanoparticles, respectively. The heat elevation of the magnetic composite were measured under various AC magnetic fields, frequency and the ambient temperatures. The temperature reached up to 46.3℃ from 36℃ at 128 Oe and 355 kHz for 20 wt.% iron oxide nanoparticles filled in PVDF fibrous composite sheet. The specific absorption rate of theses sheets increased from 0.041 W/g to 0.236 W/g with the increment of AC magnetic field from 90 Oe to 167 Oe at 190 kHz, respectively.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.221-228
Microstructure and Magnetic State of Fe3O4-SiO2 Colloidal Particles
Colloidal particles consisted of individual nanosized magnetite grains on the surface of the silica cores were obtained by two-stage sol-gel technique. Size distribution and microstructure of the particles were analyzed using atomic force microscopy, X-ray diffraction and Nitrogen thermal desorption. Magnetic properties of the particles were studied by the method of the longitudinal nonlinear response. It has been shown that nanoparticles of magnetite have a size corresponding to a superparamagnetic state but exhibit hysteresis properties. The phenomenon was explained using the magnetostatic interaction model based on the hypothesis of iron oxide particles cluster aggregation on the silica surface.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.229-240
Effect of Sintering Temperature on the Micro Strain and Magnetic Properties of Ni-Zn Nanoferrites
In this study, nanocrystalline ferrite powders with the composition Ni0.5Zn0.5Fe2O4 were prepared by the autocombustion method. The obtained powders were sintered at 800℃, 900℃ and 1,000℃ for 4 h in air atmosphere. The as-prepared and the sintered powders were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and magnetization studies. An increase in the crystallite size and a slight decrease in the lattice constant with sintering temperature were observed, whereas microstrain was observed to be negative for all the samples. Two significant absorption bands in the wave number range of the 400 cm−1 to 600 cm−1 have been observed in the FT-IR spectra for all samples which is the distinctive feature of the spinel ferrites. The force constants were found to vary with sintering temperature, suggesting a cation redistribution and modification in the unit cell of the spinel. The M-H loops indicate smaller coercivity, which is the typical nature of the soft ferrites. The observed variation in the saturation magnetization and coercivity with sintering temperature has been attributed to the role of surface, inhomogeneous cation distribution, and increase in the crystallite size.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.241-245
Synthesis of Nickel Nanoparticles using Electron Beam Irradiation
A study on the preparation of nickel oxide nanoparticles using electron beam irradiation is described. Nickel nanoparticles were synthesized with nickel chloride hexahydrate as a metal precursor and different sodium hydroxide concentrations using electron beam irradiation. The effects of sodium hydroxide concentration and electron beam absorbed doses were investigated. The samples were synthesized at different sodium hydroxide concentrations and with absorbed doses of 100 to 500 kGy at room temperature. Synthesized nanoparticles were characterized by X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) and a vibrating sample magnetometer (VSM). The nanoparticle morphologies seemed to be non-spherical and aggregated. The 1:1 molar ratio of nickel chloride hexahydrate and sodium hydroxide showed a higher purity and saturation magnetization value of 13.0 emu/g. The electron beam absorbed dose was increased with increasing nickel nanoparticle nucleation.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.246-251
Mössbauer Spectroscopic Studies of NiZn Ferrite Prepared by the Sol–Gel Method
This study was aimed to study the effect of Zn content on the hyperfine parameters and the structural variation of Ni1-xZnxFe2O4 for x = 0, 0.2, 0.4, 0.6, and 0.8. To achieve this, a sol–gel route was used for the preparation of samples and the obtained ferrites were investigated by X-ray diffraction, scanning electron microscopy, and Mössbauer spectroscopy. The formation of spinel phase without any impurity peak was identified by X-ray diffraction of all the samples. Moreover, the estimated crystallite size by X-ray line broadening indicates a decrease with increasing Zn content. This result was in agreement with the scanning electron microscopy result, indicating the reduction in grain growth with further zinc substitution. The room-temperature Mössbauer spectra show that the hyperfine fields at both the A and B sites decreased with increasing Zn content; however, the rate of reduction is not the same for different sites. Moreover, the best fit parameter showed that the quadrupole splitting values of B site increased from the pure nickel ferrite to the sample with x = 0.8.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.252-257
Analysis of Electromotive Force Characteristics for Electromagnetic Energy Harvester using Ferrofluid
This paper investigates the concept and implementation of an energy harvesting device using a ferrofluid sloshing movement to generate an electromotive force (EMF). Ferrofluids are often applied to energy harvesting devices because they have both magnetic properties and fluidity, and they behave similarly to a soft ferromagnetic substance. In addition, a ferrofluid can change its shape freely and generate an EMF from small vibrations. The existing energy harvesting techniques, for example those using piezoelectric and thermoelectric devices, generate minimal electric power, as low as a few micro-watts. Through flow analysis of ferrofluids and examination of the magnetic circuit characteristics of the resultant electromagnetic system, an energy harvester model based on an electromagnetic field generated by a ferrofluid is developed and proposed. The feasibility of the proposed scheme is demonstrated and its EMF characteristics are discussed based on experimental data.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.258-264
Extrapolating B–H Curve Data using Common Electrical Steel Characteristics for High Magnetic Saturation Applications
In this paper, an adequate B–H curve extrapolation method is proposed and its reliability is verified through experiments. A method is developed to estimate the magnetic saturation induction from the density of the lamination core and electrical resistivity. The magnetic saturation induction of electrical steels measured using a vibration sample magnetometer are compared with the analytical results to validate the accuracy of the proposed estimation method. It is found that the predicted error in the magnetic saturation induction of the electrical steels are approximately 1.2% when the proposed method is used. The performance of interior permanent magnet synchronous motors that applies the proposed method are evaluated via 2D nonlinear finite element analysis and through experiments. Based on the obtained results, the extrapolated B–H curves from the estimated saturation induction can be used for various analyses in saturation region.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.265-272
Analysis of High Torque and Power Densities Outer-Rotor PMFSM with DC Excitation Coil for In-Wheel Direct Drive
In recent years, flux switching machines (FSMs) have been an attractive research topic owing to their tremendous advantages of robust rotor structure, high torque, and high power capability suitable for intensive applications. However, most of the investigations are focusing on the inner-rotor structure, which is incongruous for direct drive applications. In this study, high torque and power densities of a new 12S-14P outer-rotor permanent magnet (PM) FSM with a DC excitation coil was investigated based on two-dimensional finite element analysis for in-wheel direct drive electric vehicle (EV). Based on some design restrictions and specifications, design refinements were conducted on the original design machine by using the deterministic optimization approach. With only 1.0 kg PM, the final design machine achieved the maximum torque and power densities of 12.4 Nm/kg and 5.93 kW/kg, respectively, slightly better than the inner-rotor HEFSM and interior PM synchronous machine design for EV.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.273-283
Analytical Solution of Magnetic Field in Permanent-Magnet Eddy-Current Couplings by Considering the Effects of Slots and Iron-Core Protrusions
In this study, we propose an analytical model for studying magnetic fields in radial-flux permanent-magnet eddy-current couplings by considering the effects of slots and iron-core protrusions on the eddy currents. We focus on the analytical prediction of the air-gap field by considering the influence of eddy currents induced in conducting bars. In the proposed model, the permanent magnet region is treated as the source of a timevarying magnetic field and the moving-conductor eddy current problem is solved based on the resolution of time-harmonic Helmholtz equations. The spatial harmonics in the air gap and in slots, as well as the time harmonics are all considered in the analytical calculation. Based on the proposed field model, the electromagnetic torque is computed by using the Maxwell stress tensor method. Nonlinear finite element analysis is performed to validate the analytical model. The proposed model can be used for permanent-magnet eddy-current couplings with any slot–pole combination.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.284-289
Modeling of a Dual Stator Induction Generator with and Without Cross Magnetic Saturation
This paper discusses general methods of modelling magnetic saturation in steady-state, two-axis (d & q) frame models of dual stator induction generators (DSIG). In particular, the important role of the magnetic coupling between the d-q axes (cross-magnetizing phenomenon) is demonstrated, with and without cross-saturation. For that purpose, two distinct models of DSIGs, with and without cross-saturation, are specified. These two models are verified by an application that is sensitive to the presence of cross-saturation, to prove the validity of these final methods and the equivalence between all developed models. Advantages of some of the models over the existing ones and their applicability are discussed. In addition, an alternative is given to evaluate all saturation factors (static and dynamic) by just calculating the static magnetizing inductance which is simply the magnitude of the ratio of the magnetizing flux to the current. The comparison between the simulation results of the proposed model with experimental results gives a good correspondence, especially at startup.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.290-294
Dependence of Alternating Magnetic Field Intensity on Proliferation Rate of Human Breast Cancer Cell
To investigate the effects of alternating magnetic field intensity and stimulation time on the proliferation of human breast cancer cells (BT-20), we cultured the cells under a magnetic field with a saw tooth waveform of 2 kHz. The field intensities varied from 3 to 7 mT, and the stimulation time varied from 24 to 72 hours. Cell proliferation decreased dramatically to 40% during magnetic stimulation for 72 hours at 5 mT. However, the cells were not affected by a strong magnetic field of 7 mT. The
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.295-301
Interference Issuses of Radio Frequency Identification Devices in Magnetic Resonance Imaging Systems and Computed Tomography Scan
We evaluated certain issues related to magnetic resonance imaging (MRI) coupled with the use of active 2.5 GHz radio frequency identification (RFID) tags for patient identification using low field (0.3 T) MRI and computed tomography (CT) scans. We also investigated the performance of the RFID reader located outside the MRI room by considering several factors. A total of ten active RFID tags were exposed to several MRI sequences and X-rays of CT scan. We found that only card type active RFID tags are suitable for patient identification purpose in MRI environment and both wristbands as well as card tags were suitable for the same in CT environment. Severe artifacts were found in the captured MRI and CT images when the area of the imaging was in proximity to the tags. No external factors affected the performance of active RFID reader stationed outside the MRI scan room.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.302-307
Influence of Iodinated Magnetic Resonance Contrast Media and Isotope 99mTc on Changes of Computed Tomography Number
The purpose of the study was to identify how isotope and magnetic resonance imaging (MRI) contrast media impact on noise to computed tomography (CT) examination. For the study, divide the phantoms to two groups: 1) saline, saline + different kinds of contrast agent without 99mTc administration; 2) 99mTc administration: saline, saline + different kinds of contrast agent with 99mTc administration. CT contrast agent was used for Iopamidol® and Dotarem. And MRI contrast agent was used for Primovist® and Gadovist®. To obtain an image, we used CT scanner. With an obtained image, we set the 1 cm2 region of interest in the middle of bottle to measure the noise and CT number. As a result, there was no difference in CT number before and after inserting 99mTc into all contrast media including Normal Saline. However, when it comes to Noise, there was a difference before and after inserting 99mTc into every contrast media except MRI contrast media such as Primovist® and Gadovist® .
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.308-311
Design of Crisscrossed Double-Layer Birdcage Coil for Improving B1+ Field Homogeneity for Small-Animal Magnetic Resonance Imaging at 300 MHz
We design a crisscrossed double-layer birdcage (DLBC) coil by modifying the coil geometry of a standard single-layer BC (SLBC) coil to enhance the homogeneity of transmitting magnetic flux density (B1+) along the main magnetic field (B0)-direction for small-animal magnetic resonance imaging (MRI) at 300 MHz. The performance assessment of the crisscrossed DLBC coil is conducted by computational analysis with the finitedifference time domain method (FDTD) and compared with SLBC coil in terms of the B1 and the B1distribution. As per the computational calculation studies, the mean value in the two-dimensional B1+ map obtained at the mid-axial slice with the proposed DLBC coil is slightly lower than that obtained with the SLBC coil, but the B1+ value of the DLBC coil in the outermost plane (40 mm away from the central plane) shows improvements of 19.3% and 24.8% over the SLBC coil B1+ value when simulating a spherical phantom and realistic mouse body modeling. These simulation results indicate that, the B1+ homogeneity along the z-direction was improved by using DLBC configuration. Our approach enables B1+ homogeneity improvement along the zdirection, and it can also be applied to ultra-high field (UHF) MRI systems.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.312-316
Detection of Deep Subsurface Cracks in Thick Stainless Steel Plate
Unlike conventional Eddy Current Test (ECT), Pulsed Eddy Current (PEC) uses a multiple-frequency current pulse through the excitation coil. In the present study, the detection of subsurface cracks using a specially designed probe that allows the detection of a deeper crack with a relatively small current density has been attempted using the PEC technique. The tested sample is a piece of 304 stainless steel (SS304) with a thickness of 30mm. Small electrical discharge machining (EDM) notches were put in the test sample at different depths from the surface to simulate the subsurface cracks in a pipe. The designed PEC probe consists of an excitation coil and a Hall sensor and can detect a subsurface crack as narrow and shallow as 0.2 mm wide and 2 mm deep. The maximum distance between the probe and the defect is 28 mm. The peak amplitude of the detected pulse is used to evaluate the cracks under the sample surface. In time domain analysis, the greater the crack depth the greater the peak amplitude of the detected pulse. The experimental results indicated that the proposed system has the potential to detect the subsurface cracks in stainless steel plates.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.317-321
Influence of Oleic and Lauric Acid on the Stability of Magnetorheological Fluids
In this paper, magnetorheological fluids (MRFs) based on micro-sized iron particles dispersed in silicone oil are presented. The iron particles are modified by adding different ratios of oleic acid and lauric acid as surfactants to the suspensions. Lauric acid was found to reduce the stability of the MRFs, and more lauric acid results in a higher rate of sedimentation. Further study showed that the formation and structure of lauric acid may result in the sedimentation of micrometer-sized particles. Meanwhile, the electro-resistance of MRF in this paper shows a decrease from beyond 6000 MΩ to 190 Ω with an increase in the external field from 0 mT to 400 mT.
Journal of Magnetics, 31 Aug 2015, Vol.20 , No.3, pp.322-329
Overlapped Electromagnetic Coilgun for Low Speed Projectiles
This paper presents a new overlapped coilgun configuration to launch medium weight projectiles. The proposed configuration consists of a two-stage coilgun with overlapped coil covers with spacing between them. The theoretical operation of a multi-stage coilgun is introduced, and a transient simulation was conducted for projectile motion through the launcher by using a commercial transient finite element software, ANSOFT MAXWELL. The excitation circuit design for each coilgun is reported, and the results indicate that the overlapped configuration increased the exit velocity relative to a non-overlapped configuration. Different configurations in terms of the optimum length and switching time were attempted for the proposed structure, and all of these cases exhibited an increase in the exit velocity. The exit velocity tends to increase by 27.2% relative to that of a non-overlapped coilgun of the same length.